Effect of Plasticizer Type on Properties, Structure and Application Effect of Pullulan-Soluble Soybean Polysaccharide Film

ZHAO Fan; JIANG Lijun; LI Shuangdie; WANG Chenyu; SUN Di; LIU Yu; JIANG Wei

doi:10.13386/j.issn1002-0306.2024020111

Volume 46 Issue 5

Feb. 2025

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Science and Technology of Food Industry > 2025 > 46(5): 35-43. > DOI: 10.13386/j.issn1002-0306.2024020111

ZHAO Fan, JIANG Lijun, LI Shuangdie, et al. Effect of Plasticizer Type on Properties, Structure and Application Effect of Pullulan-Soluble Soybean Polysaccharide Film[J]. Science and Technology of Food Industry, 2025, 46(5): 35−43. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2024020111.

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Effect of Plasticizer Type on Properties, Structure and Application Effect of Pullulan-Soluble Soybean Polysaccharide Film

ZHAO Fan^1,,
JIANG Lijun²,
LI Shuangdie¹,
WANG Chenyu²,
SUN Di¹,
LIU Yu^{1, 2, ,},
JIANG Wei^{1, 2, ,}

1.
National Engineering Research Center for Marine Aquaculture, Zhejiang Ocean University, Zhoushan 316022, China
2.
College of Food and Pharmacy, Zhejiang Ocean University, Zhoushan 316022, China

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Received Date: February 19, 2024
Available Online: December 24, 2024

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Abstract

Abstract

In order to improve the flexibility and heat-sealing performance of pullulan-soluble soybean polysaccharide film and its application potential, the effects of four plasticizers (polyethylene glycol, propylene glycol, glycerol and sorbitol) on the physical properties, structure and application effect of pullulan-soluble soybean polysaccharide film were studied in this article. Compared to the pullulan-soluble soybean polysaccharide film without plasticizer, the film with plasticizer showed increase in thickness, moisture content and elongation at break, and decrease in brightness (P<0.05). The propylene glycol, glycerol, and sorbitol films had smooth surfaces and uniform, compact structures. The polyethylene glycol film had a rough surface and porous structure, with a significant decrease in light transmittance and heat-sealing strength (P<0.05). The propylene glycol film showed a decrease in water contact angle, but no significant changes in light transmittance, dissolution time, and heat-sealing strength were observed. The glycerol and sorbitol films showed a higher elongation at break than other films, with a significantly decrease in water contact angle and dissolution time (P<0.05) and a significantly increase in heat-sealing strength (P<0.05). The results of the peptide powder packaging application indicated that the glycerol film showed the best heat-sealing form and instant effect. In summary, glycerol film exhibits good solubility (dissolution time<30 s), high flexibility (high elongation at break), and significant higher heat-sealing strength (2.58 N/15 mm) (P<0.05) compared to other films, and has potential applications as a heat-sealing instant film.
- plasticizer,
- pullulan-soluble soybean polysaccharide film,
- mechanical properties,
- quick-dissolving,
- heat-seal

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References (36)

References

[1]	MENG W K, SUN H, SU G Y. Plastic packaging-associated chemicals and their hazards – An overview of reviews[J]. Chemosphere,2023,331:138795. doi: 10.1016/j.chemosphere.2023.138795
[2]	申志翔. 玉米—小麦淀粉复合可食用膜的研究与应用[D]. 郑州:河南工业大学, 2018. [SHEN Z X. Research and application of corn - wheat starch compound edible film[D]. Zhengzhou:Henan University of Technology, 2018.] SHEN Z X. Research and application of corn - wheat starch compound edible film[D]. Zhengzhou: Henan University of Technology, 2018.
[3]	QUILEZ-MOLINA A I, MAZZON G, ATHANASSIOU A, et al. A novel approach to fabricate edible and heat sealable bio-based films from vegetable biomass rich in pectin[J]. Materials Today Communications,2022,32:103871. doi: 10.1016/j.mtcomm.2022.103871
[4]	谢彩玲, 梅小虎, 郭艳峰. 方便食品可食性调料包装性能研究[J]. 食品安全导刊,2021(19):150−154. [XIE C L, MEI X H, GUO Y F. Research on the packaging performance of edible seasonings for convenience food[J]. China Food Safety Magazine,2021(19):150−154.] XIE C L, MEI X H, GUO Y F. Research on the packaging performance of edible seasonings for convenience food[J]. China Food Safety Magazine, 2021（19）: 150−154.
[5]	潘旭琳, 马萍, 刘伟, 等. 胡萝卜可食性包装膜的制备及性能[J]. 包装工程,2021,42(21):58−64. [PAN X L, MA P, LIU W, et al. Preparation and property of carrot edible film[J]. Packaging Engineering,2021,42(21):58−64.] PAN X L, MA P, LIU W, et al. Preparation and property of carrot edible film[J]. Packaging Engineering, 2021, 42（21）: 58−64.
[6]	LOPES J, PETTERSEN M K, GRØVLEN M S, et al. Heat-sealable bioplastic films of blended locust bean and potato byproducts for active packaging of fatty foods:Cheese and oat cookies as case studies[J]. Food Hydrocolloids,2024,147:109322. doi: 10.1016/j.foodhyd.2023.109322
[7]	周凤. 魔芋葡甘聚糖/普鲁兰糖活性混合膜的制备、表征及应用[D]. 雅安:四川农业大学, 2023. [ZHOU F. Preparation, characterization and application of konjac glucomannan/pullulan active blend films[D]. Yaan:Sichuan Agricultural University, 2023.] ZHOU F. Preparation, characterization and application of konjac glucomannan/pullulan active blend films[D]. Yaan: Sichuan Agricultural University, 2023.
[8]	DONG Y T, LI Y J, MA Z X, et al. Effect of polyol plasticizers on properties and microstructure of soluble soybean polysaccharide edible films[J]. Food Packaging and Shelf Life,2023,35:101023. doi: 10.1016/j.fpsl.2022.101023
[9]	马正欣. 纳米银/多糖抗菌复合材料的构建与性能研究[D]. 郑州:郑州大学, 2022. [MA Z X. Construction and performance of silver nanoparticles/polysaccharide antibacterial composite materials[D]. Zhengzhou:Zhengzhou University, 2022.] MA Z X. Construction and performance of silver nanoparticles/polysaccharide antibacterial composite materials[D]. Zhengzhou: Zhengzhou University, 2022.
[10]	ZHANG N, LI X H, YE J, et al. Effect of gellan gum and xanthan gum synergistic interactions and plasticizers on physical properties of plant-based enteric polymer films[J]. Polymers,2020,12(1):121. doi: 10.3390/polym12010121
[11]	HORN M M, AMARO MARTINS V C, DE GUZZI PLEPIS A M. Characterization of films and film-forming solutions of chitosan/thermoplastic rice starch associations:Role of starch oxidation and plasticizer type in the molecular interactions[J]. Polymer Engineering & Science,2023,63(12):4127−4139.
[12]	CAICEDO C, DÍAZ-CRUZ C A, JIMÉNEZ-REGALADO E J, et al. Effect of plasticizer content on mechanical and water vapor permeability of maize starch/PVOH/chitosan composite films[J]. Materials,2022,15(4):1274. doi: 10.3390/ma15041274
[13]	胥亮. 可得然胶活性可食膜的结构、性能及应用研究[D]. 扬州:扬州大学, 2023. [XU L. Study on the structure, properties and application of curdlan active edible film[D]. Yangzhou:Yangzhou University, 2023.] XU L. Study on the structure, properties and application of curdlan active edible film[D]. Yangzhou: Yangzhou University, 2023.
[14]	方春姗, 姜维, 胡艺, 等. 基于美拉德反应的大豆分离蛋白改性膜的制备及应用研究[J]. 食品安全质量检测学报,2023,14(7):241−249. [FANG C S, JIANG W, HU Y, et al. Preparation and application of soybean protein isolate modified film based on Maillard reaction[J]. Journal of Food Safety and Quality,2023,14(7):241−249.] FANG C S, JIANG W, HU Y, et al. Preparation and application of soybean protein isolate modified film based on Maillard reaction[J]. Journal of Food Safety and Quality, 2023, 14（7）: 241−249.
[15]	HUANG X, LUO X, LIU L, et al. Formation mechanism of egg white protein/κ-carrageenan composite film and its application to oil packaging[J]. Food Hydrocolloids,2020,105:105780. doi: 10.1016/j.foodhyd.2020.105780
[16]	LIU J, MA Z X, LIU Y C, et al. Soluble soybean polysaccharide films containing in-situ generated silver nanoparticles for antibacterial food packaging applications[J]. Food Packaging and Shelf Life,2022,31:100800. doi: 10.1016/j.fpsl.2021.100800
[17]	ZHENG K W, WU Y Y, DAI Q F, et al. Extraction, identification, and molecular mechanisms of α-glucosidase inhibitory peptides from defatted Antarctic krill (Euphausia superba) powder hydrolysates[J]. International Journal of Biological Macromolecules,2024,266:131126. doi: 10.1016/j.ijbiomac.2024.131126
[18]	LIU C, HUANG J, ZHENG X J, et al. Heat sealable soluble soybean polysaccharide/gelatin blend edible films for food packaging applications[J]. Food Packaging and Shelf Life,2020,24:100485. doi: 10.1016/j.fpsl.2020.100485
[19]	黄依然, 陈晓婷, 潘南, 等. 添加剂改性玉米醇溶蛋白复合膜的制备与表征[J]. 精细化工,2022,39(12):2431−2440, 2423. [HUANG Y R, CHEN X T, PAN N, et al. Preparation and characterization of additive-modified zein composite films[J]. Fine Chemicals,2022,39(12):2431−2440, 2423.] HUANG Y R, CHEN X T, PAN N, et al. Preparation and characterization of additive-modified zein composite films[J]. Fine Chemicals, 2022, 39（12）: 2431−2440, 2423.
[20]	GUO S X, FU Z Q, SUN Y, et al. Effect of plasticizers on the properties of potato flour films[J]. Starch – Stä rke,2022,74(1–2):2100179.
[21]	ILI BALQIS A M, NOR KHAIZURA M A R, RUSSLY A R, et al. Effects of plasticizers on the physicochemical properties of kappa-carrageenan films extracted from Eucheuma cottonii[J]. International Journal of Biological Macromolecules,2017,103:721−732. doi: 10.1016/j.ijbiomac.2017.05.105
[22]	向飞, 李冲, 夏玉婷, 等. 纳米TiO₂对魔芋葡甘聚糖/玉米醇溶蛋白复合膜结构和性能的影响[J]. 食品工业科技,2021,42(9):221−227. [XIANG F, LI C, XIA Y T, et al. Effect of nano titanium dioxide on the structure and properties of KGM/zein blend films[J]. Science and Technology of Food Industry,2021,42(9):221−227.] XIANG F, LI C, XIA Y T, et al. Effect of nano titanium dioxide on the structure and properties of KGM/zein blend films[J]. Science and Technology of Food Industry, 2021, 42（9）: 221−227.
[23]	APHIBANTHAMMAKIT C, NIGEN M, GAUCEL S, et al. Surface properties of Acacia senegal vs Acacia seyal films and impact on specific functionalities[J]. Food Hydrocolloids,2018,82:519−533. doi: 10.1016/j.foodhyd.2018.04.032
[24]	SHEN Y, ZHOU J, YANG C, et al. Preparation and characterization of oregano essential oil-loaded Dioscorea zingiberensis starch film with antioxidant and antibacterial activity and its application in chicken preservation[J]. International Journal of Biological Macromolecules,2022,212:20−30. doi: 10.1016/j.ijbiomac.2022.05.114
[25]	EL MIRI N, AZIZ F, ABOULKAS A, et al. Effect of plasticizers on physicochemical properties of cellulose nanocrystals filled alginate bionanocomposite films[J]. Advances in Polymer Technology,2018,37(8):3171−3185. doi: 10.1002/adv.22087
[26]	王之强, 王远哲, 王静伊, 等. 不同增塑剂对结冷胶薄膜性能的影响[J]. 食品与发酵工业,2023,49(9):186−193. [WANG Z Q, WANG Y Z, WANG J Y, et al. Effects of different plasticizers on properties of gellan gum films[J]. Food and Fermentation Industries,2023,49(9):186−193.] WANG Z Q, WANG Y Z, WANG J Y, et al. Effects of different plasticizers on properties of gellan gum films[J]. Food and Fermentation Industries, 2023, 49（9）: 186−193.
[27]	ABDORREZA M N, CHENG L H, KARIM A A. Effects of plasticizers on thermal properties and heat sealability of sago starch films[J]. Food Hydrocolloids,2011,25(1):56−60. doi: 10.1016/j.foodhyd.2010.05.005
[28]	LIM W S, OCK S Y, PARK G D, et al. Heat-sealing property of cassava starch film plasticized with glycerol and sorbitol[J]. Food Packaging and Shelf Life,2020,26:100556. doi: 10.1016/j.fpsl.2020.100556
[29]	FARHAN A, HANI N M. Characterization of edible packaging films based on semi-refined kappa-carrageenan plasticized with glycerol and sorbitol[J]. Food Hydrocolloids,2017,64:48−58. doi: 10.1016/j.foodhyd.2016.10.034
[30]	LIAO W, LIU X, ZHAO Q, et al. Physicochemical, antibacterial and food preservation properties of active packaging films based on chitosan/ε-polylysine-grafted bacterial cellulose[J]. International Journal of Biological Macromolecules,2023,253:127231. doi: 10.1016/j.ijbiomac.2023.127231
[31]	ALIOUI O, SOBHI W, TIECCO M, et al. Theoretical and experimental evidence for the use of natural deep eutectic solvents to increase the solubility and extractability of curcumin[J]. Journal of Molecular Liquids,2022,359:119149. doi: 10.1016/j.molliq.2022.119149
[32]	刘畅. 水溶性大豆多糖基复合膜的制备与性能研究[D]. 郑州:郑州大学, 2021. [LIU C. Study on the preparation and properties of composite films based on soluble soybean polysaccharide[D]. Zhengzhou:Zhengzhou University, 2021.] LIU C. Study on the preparation and properties of composite films based on soluble soybean polysaccharide[D]. Zhengzhou: Zhengzhou University, 2021.
[33]	葛婷婷, 宋永明, 刘迎涛. 增塑剂对细菌纳米纤维素-壳聚糖复合膜性能的影响[J]. 东北林业大学学报,2021,49(2):112−116. [GE T T, SONG Y M, LIU Y T, et al. Effects of plasticizer on the properties of bacterial nanocellulose/chitosan composite film[J]. Journal of Northeast Forestry University,2021,49(2):112−116.] GE T T, SONG Y M, LIU Y T, et al. Effects of plasticizer on the properties of bacterial nanocellulose/chitosan composite film[J]. Journal of Northeast Forestry University, 2021, 49（2）: 112−116.
[34]	方超逸, 肖菲菲, 陈宇桦, 等. 负载儿茶素的聚乙烯醇/壳聚糖电纺膜的构建及性能分析[J]. 食品工业科技,2024,45(4):10−23. [FANG C Y, XIAO F F, CHEN Y H, et al. Construction and properties of polyvinyl alcohol/chitosan electrospun film loaded with catechins[J]. Science and Technology of Food Industry,2024,45(4):10−23.] FANG C Y, XIAO F F, CHEN Y H, et al. Construction and properties of polyvinyl alcohol/chitosan electrospun film loaded with catechins[J]. Science and Technology of Food Industry, 2024, 45（4）: 10−23.
[35]	鞠阳, 郑秀霞, 段嘉婧, 等. 淀粉醛强化大豆分离蛋白/槲皮素复合膜制备及性能研究[J]. 食品安全质量检测学报,2024,15(1):135−145. [JU Y, ZHENG X X, DUAN J J, et al. Preparation and properties of soybean isolate protein/quercetin composite film fortified with dialdehyde starch[J]. Journal of Food Safety and Quality,2024,15(1):135−145.] JU Y, ZHENG X X, DUAN J J, et al. Preparation and properties of soybean isolate protein/quercetin composite film fortified with dialdehyde starch[J]. Journal of Food Safety and Quality, 2024, 15（1）: 135−145.
[36]	DONG Y, RAO Z, LIU Y, et al. Soluble soybean polysaccharide/gelatin active edible films incorporated with curcumin for oil packaging[J]. Food Packaging and Shelf Life,2023,35:101039. doi: 10.1016/j.fpsl.2023.101039

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Science and Technology of Food Industry

Effect of Plasticizer Type on Properties, Structure and Application Effect of Pullulan-Soluble Soybean Polysaccharide Film

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